Search results for "Excitation spectra"
showing 10 items of 13 documents
Low-temperature luminescence of CdI2 under synchrotron radiation
2020
Synchrotron radiation is applied to study visible and UV luminescence spectra and their excitation spectra of undoped as well as In and Sb doped cadmium iodide crystals at 10 K. The origin of principal luminescence bands and the role of impurities in the formation of emission centers are discussed. The luminescence properties have been explained based on the electronic structure of CdI2 crystals.
A Theoretical Study of the Low-Lying Excited States of trans- and cis-Urocanic Acid
1999
A multiconfigurational second-order perturbation theory (CASPT2) study of the lowest lying states in the gas-phase electronic spectra of trans- and cis-urocanic acid is presented. Geometries of both isomers have been optimized at the MP2/6-31G(d) and π-CASSCF/ANO-L(4s3p1d,2s) levels of theory. The geometries are found to differ considerably between the two levels. The vertical and 0−0 excitation spectra were calculated for each isomer. Both singlet and triplet states are described for each, including the lowest lying ππ* excitations and the nOπ* excitations. Remarkably, in the trans spectrum, it is found that the nOπ* state has a higher vertical excitation energy than the lowest ππ* (5.12 v…
Fluoreszenz‐Untersuchungen an styrylsubstituierten Benzolen
1986
Die Fluoreszenz-Abklingzeiten der stilbenartigen Verbindungen 1 – 4 zeigen, das die mittleren Lebensdauern dieser Molekule im elektronisch angeregten Singulettzustand um rund zwei Zehnerpotenzen hoher sind als bei trans-Stilben selbst. Anhand von UV-Absorptions-und Anregungsspektren wird das auf einen neu gefundenen S1-Zustand zuruckgefuhrt, der einem verbotenen Ubergang S0 S1 auf der langwelligen Seite der intensiven Absorption entspricht. Investigations on the Fluorescence of Styryl-substituted Benzenes Fluorescence decay measurements of the stilbene-like compounds 1 – 4 demonstrate that the average lifetimes of these molecules in the electronically excited singlet state are about 102 tim…
Gamow–Teller beta decays of the odd-mass neighbors of the solar-neutrino detector 127I
2002
Abstract Calculations of the energy spectra and the log ft values of Gamow–Teller beta transitions of neutron-odd and proton-odd nuclei close to the solar-neutrino detector 127I are performed using the microscopic quasiparticle–phonon model. The information obtained from the beta transition strengths is valuable in solar-neutrino detection and dark matter search both in present and future large-scale experiments. Realistic interactions within a realistic single-particle valence space were used in the calculations. The overall correspondence in terms of the excitation spectra and the log ft values between theory and experiments can be regarded as quite good when considering the completely mi…
Electron spectra in forbidden β decays and the quenching of the weak axial-vector coupling constant gA
2017
Evolution of the electron spectra with the effective value of the weak axial-vector coupling constant ${g}_{\mathrm{A}}$ was followed for 26 first-, second-, third-, fourth- and fifth-forbidden ${\ensuremath{\beta}}^{\ensuremath{-}}$ decays of odd-$A$ nuclei by calculating the involved nuclear matrix elements (NMEs) in the framework of the microscopic quasiparticle-phonon model (MQPM). The next-to-leading-order terms were included in the $\ensuremath{\beta}$-decay shape factor of the electron spectra. The spectrum shapes of third- and fourth-forbidden nonunique decays were found to depend strongly on the value of ${g}_{\mathrm{A}}$, while first- and second-forbidden decays were mostly unaff…
Spin-coupling topology in the copper hexamer compounds A2Cu3O(SO4)3 (A=Na, K)
2020
The compounds ${A}_{2}\mathrm{C}{\mathrm{u}}_{3}\mathrm{O}{(\mathrm{S}{\mathrm{O}}_{4})}_{3}$ $(A=\mathrm{Na},\phantom{\rule{0.16em}{0ex}}\mathrm{K})$ are characterized by copper hexamers that are weakly coupled to realize antiferromagnetic order below ${T}_{N}\ensuremath{\approx}3\phantom{\rule{0.16em}{0ex}}\mathrm{K}$. They constitute quantum spin systems with $S=1$ triplet ground states. We investigated the energy-level splittings of the copper hexamers by inelastic neutron scattering experiments covering the entire range of the magnetic excitation spectra. The observed transitions are governed by very unusual selection rules that we ascribe to the underlying spin-coupling topology. This…
The Kadanoff–Baym approach to double excitations in finite systems
2011
We benchmark many-body perturbation theory by studying neutral, as well as non-neutral, excitations of finite lattice systems. The neutral excitation spectra are obtained by time-propagating the Kadanoff-Baym equations in the Hartree-Fock and second Born approximations. Our method is equivalent to solving the Bethe-Salpeter equation with a high-level kernel while respecting self-consistently, which guarantees the fulfillment of a frequency sum rule. As a result, we find that a time-local method, such as Hartree-Fock, can give incomplete spectra, while already the second Born, which is the simplest time-nonlocal approximation, reproduces well most of the additional excitations, which are cha…
PRODUCTION OF Θ+ HYPERNUCLEI WITH THE (K+, π+) REACTION
2005
Abstract We present results on the production of bound states of Θ + in nuclei using the ( K + , π + ) reaction. By taking into account the states obtained within a wide range of strength of the Θ + nucleus optical potential, plus the possibility to replace different nucleons of the nucleus, we obtain an excitation spectra with clearly differentiated peaks. The magnitude of the calculated cross sections is well within reachable range.
STABILITY AND SPECTRA OF SMALL 3He-4He CLUSTERS
2005
Diffusion Monte Carlo calculations have been systematically performed to analyze the stability of small mixed 3 He -4 He clusters, as well as their excitation spectra. The picture that emerges is that of systems with strong shell effects whose binding and excitation energies are essentially determined by the monopole properties of an effective Hamiltonian.
Optical determination of pH on surfaces using immobilized Fluorescent dyes.
1993
The attachment of pH-sensitive Fluorescent dyes on to hydroxylapatite for measuring the pH of small volumes is described. Fluorescein and acridine were used, both activated with reactive functions, such as isothiocyanate or succinimidyl ester groups, to enhance the possibility of a covalent linkage to the surface. First investigations were carried out on synthetic hydroxylapatite as the surface material. After the preparation of a particular surface with the fluorescent dye, steady-state and time-resolved fluorescence spectroscopies were employed for estimating the pH value of a solution applied to the surface. In this paper we present the results of our investigations done with both method…